Although the content of the Conference was unquestionably well prepared, some organizational problems appeared.

unquestionably 是由形容词 questionable（有疑问的）加上否定前缀 un-（表示"不"）和副词后缀 -ly 构成的副词。questionable 来自名词 question（问题），所以 unquestionably 字面意思是"没有问题地"，即"毫无疑问地"。